Guerlain

No one saw this coming: Angelina Jolie stars as the new face for Guerlain Beauty.  The new fragrance, Mon Guerlain, was cooked up by Guerlain Master Perfumer Jacques Guerlain with the supermom in mind. His influence for Mon Guerlain were the "notes of a woman" — "the choices, emotions and dreams that embody modern femininity."  Yup 100% baddass sexy.

And not to mention she will be given her entire earning from the Guerlain campaign to charity.  Beauty for life and for the entire population.  Kudos to Angelina.